Semiconductor device having improved contacts

ABSTRACT

A device with a solder joint made of a copper contact pad ( 210 ) of certain area ( 202 ) and an alloy layer ( 301 ) metallurgically attached to the copper pad across the pad area. The alloy layer contains copper/tin alloys, which include Cu 6 Sn 5  intermetallic compound, and nickel/copper/tin alloys, which include (Ni,Cu) 6 Sn 5  intermetallic compound. A solder element ( 308 ) including tin is metallurgically attached to the alloy layer across the pad area. No fraction of the original thin nickel layer is left after the reflow process. Copper/tin alloys help to improve the drop test performance, nickel/copper/tin alloys help to improve the life test performance.

This application is a continuation of application Ser. No. 11/201,717filed Aug. 11, 2005, which is now U.S. Pat. No. 7,233,074, the contentsof which are herein incorporated by reference in its entirety.

FIELD OF THE INVENTION

The present invention is related in general to the field ofmetallurgical systems with application to electronic systems andsemiconductor devices, and more specifically to the structure ofsemiconductor devices with copper-metallized contact pads and theirreliability under accelerated stress tests.

DESCRIPTION OF THE RELATED ART

Among the semiconductor device packages for surface mount assembly, ballgrid array (BGA) packages enjoy an ever increasing popularity. They canbe used in many customer products and lend themselves to the ongoingtrend of miniaturization. The solder elements, distributed over thewhole package area, offer high numbers of input/output terminals. Inaddition, the solder elements offer the opportunity of board attachtechnology at very low failure rate (“6 sigma processing”).

Recently, however, there are challenging requirements affecting BGApackages. To name just a few: More and more, the solder elements arerequired to be free of lead (for environmental reasons); thisrequirement causes metallurgical challenges. The contact pads havecopper as its base metal; this choice creates metallurgical interfacechallenges for the solder elements. The ever decreasing feature size ofthe package components creates new hurdles to pass the acceleratedstress tests at acceptable survival rates; for instance, acceleratedlife tests at elevated temperatures and in moist environment become morechallenging. Device products containing BGA packages are spreading intomore and more customer applications; often, these applications createmore stringent or even altogether new acceptance tests. As a recentexample, wireless phone applications brought about the requirement towithstand phone drop tests in order to demonstrate that the solderjoints of the BGA packages remain reliable after the test.

SUMMARY OF THE INVENTION

Applicant recognizes a need for a flexible, yet low-cost and robustmethodology to fabricate devices with solder joints, especiallysemiconductor packages, so that the joints bestow application-specificmechanical and thermal reliability to the devices and the devices willpass product-specific tests.

One embodiment of the invention is a device with a solder joint made ofa contact pad of certain area and an alloy layer metallurgicallyattached to the contact pad across the pad area. The surface of thecontact pad has copper. The alloy layer includes copper/tin alloys andcopper/nickel/tin alloys over the contact area. The copper/tin alloysinclude Cu₆Sn₅ intermetallic compound. The copper/nickel/tin alloysinclude (Ni,Cu)₆Sn₅ intermetallic compound. A solder element includingtin is metallurgically attached to the alloy layer across the pad area.

The first alloys, dominated by copper/tin alloys, help to improve thedrop test performance to the best level achieved by solder joints withcopper pads. The second alloys, dominated by nickel-containing alloys,help to improve the life test performance by slowing the agingconditions.

A preferred method of forming the desired number, distribution, andthickness of the alloy regions in the above-described embodiment is todeposit a thin nickel layer of pre-determined thickness over the coppercontact pad, to attach a tin-containing solder element to the nickellayer, and to reflow the solder according to a selected time-temperatureprofile.

In another embodiment of the invention, the alloy layer may include goldor palladium.

The technical advantages represented by certain embodiments of theinvention will become apparent from the following description of thepreferred embodiments of the invention, when considered in conjunctionwith the accompanying drawings and the novel features set forth in theappended claims.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 illustrates a schematic cross section of a semiconductor deviceof the ball grid array (BGA) type having solder elements for externalconnections.

FIG. 2 is a schematic cross section of portion “A” (FIG. 1) of thesubstrate showing the detail of a contact pad before solder elementattachment.

FIG. 3 is a schematic cross section of portion “A” (FIG. 1) of thesubstrate showing the detail of a contact pad after reflow of the solderelement.

FIG. 4 is a schematic cross section of portion “B” (FIG. 3) of a solderjoint.

FIG. 5 illustrates an example of a time-temperature profile for a coppercontact with a thin nickel layer to reflow tin solder and createcopper/tin and nickel/tin, nickel/copper/tin alloy regions.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

FIG. 1 illustrates schematically a representative of the large family ofball grid array (BGA) semiconductor devices. Semiconductor chip 101 isassembled on substrate 102 by using chip attach material 103 formechanical attachment and bonding wires 104 for electrical connections.The assembly is encapsulated, typically in molding compound 105.

Substrate 102 has one or more patterned metal layers for internalinterconnection (not shown in FIG. 1), especially to create connectinglines between the wire stitch bond sites 106 and the contact pads 107for external connections. The metal layers are separated by insulatinglayers. Solder elements 108 are attached to the contact pads 107. Thereliability of this solder attachment under various test and useconditions deserves special consideration.

Portion “A” of the device is shown in more detail in FIGS. 2 and 3. FIG.2 illustrates a device contact pad before the reflow of solder element208, and FIG. 3 after the reflow process. In FIG. 2, substrate 102 hasan insulating surface layer 201, which is often referred to as a soldermask. A window of width 202 has been opened in solder mask 201, whichexposes a portion of the interconnecting metallization 210 of thesubstrate and thus defines the contact area. Metallization 210 is madeof copper, and the area of the exposed copper is determined by the width202 of the solder mask window.

A layer 211 of nickel is deposited over the area of the exposed copper;in addition, a layer 212 of a noble metal such as gold or palladium isdeposited over the nickel layer. The thickness of the nickel layer inthis embodiment is between about 0.01 and 0.3 μm; a preferred thicknessrange is 0.12±0.04 μm. The thickness of the gold layer is between about0.1 and 1.0 μm; a preferred thickness range is 0.5±0.25 μm.

Solder reflow element 208 contains tin; in addition, it may contain oneor more of the metals selected from a group consisting of lead, silver,bismuth, indium, zinc, copper, nickel and antimony. For the nickel layerthickness in this embodiment, the amount of tin, and other reflowmetals, in reflow element 208 is much larger than the amount of nickel.

As FIG. 2 shows, substrate 102 has one or more pads 220 on the substratesurface opposite to the contact pad 202; these pads serve as bond padsfor the connection wires 230 to the semiconductor chip bond pads. Sincewire 230 is preferably made of gold and pad 220 preferably is intendedfor gold wire stitches 231, pad 220 is preferably made of a stack oflayers including copper layer 221, nickel layer 222, and gold layer 223.

FIG. 3 illustrates the device contact pad after the reflow of the solderelement 208. 210 is the copper line with the contact pad exposed by thewindow of width 202 in solder resist 201. Width 202 defines the coppercontact area.

Metallurgically attached to the copper, across the area, is an alloylayer 301, which includes tin, copper and nickel. Region “B” of FIG. 3is enlarged in FIG. 4. In order to achieve the best reliabilityperformance, the alloy should consume the entire deposited nickel layerin the contact area. Metallurgically attached to alloy layer 301 isreflow element 308 with tin as its main component.

In FIG. 4, on an insulating portion of substrate 102 is a portion of thecopper layer 210 in the copper contact area. Metallurgically attached tocopper layer 210 is alloy layer 301, and metallurgically attached toalloy layer 301 is a portion of reflow element 308, containing mainlytin.

Alloy layer 301 comprises copper/tin alloys and copper/nickel/tinalloys. The copper/tin alloys comprise a high percentage of Cu₆Sn₅intermetallic compound, frequently in scallop-type outline. Thenickel/copper/tin alloys comprise a high percentage of (Ni, Cu)₆Sn₅intermetallic compound, frequently with crystallites spalled off intothe alloy layer.

In embodiments, which have gold as a component of the alloys, the alloyscomprise a high percentage of (Cu, Ni, Au)₆Sn₅ intermetallic compound.With the latter intermetallic compound, the thickness of the alloy layeris preferably between 2.0 and 3.0 μm.

The nickel-containing alloys have consumed all available nickel from theoriginal nickel layer so that no fraction of the nickel layer is leftafter the alloy formation (reflow) process.

A pre-determined ratio between copper/tin alloys and nickel/copper/tinalloys can be manufactured by selecting the values of two parameters:the thickness of the nickel layer and the time-temperature profile ofthe reflow process. An example of a preferred time-temperature sequence501 for a nickel layer in the 0.1±0.05 μm thickness range is reproducedin FIG. 5 (temperature measured in ° C., time in minutes). As can beseen, the profile has a pre-heat range 501 between about 130 and 170° C.of about 1 to 2 min, and a high temperature range 502 above about 230°C. of about ¼ to ¾ min.

Quantitative investigations by the inventor have shown that copper/tinalloys help to improve the drop test performance of the assembled deviceto the best level achieved by solder joints with copper pads. On theother hand, nickel-containing alloys, obtained from a starting nickellayer thickness of approximately 0.1 μm, improve the life testperformance of the finished device characteristics by slowing the agingconditions so much that the device characteristics remain approximatelyconstant over the expected device life span.

In other embodiments of the invention, the alloy layer 301 together withthe reflowed tin solder element 308 may include dissolved noble metalssuch as gold or palladium. The noble metal, shown in FIG. 2 as adeposited layer, is dissolved in the process step of reflowing.

While this invention has been described in reference to illustrativeembodiments, this description is not intended to be construed in alimiting sense. Various modifications and combinations of theillustrative embodiments, as well as other embodiments of the invention,will be apparent to persons skilled in the art upon reference to thedescription. As an example, even thinner nickel layers may beemployed—just enough nickel to shield the copper from oxidation. It istherefore intended that the appended claims encompass any suchmodification.

1. A device comprising: a semiconductor chip; a substrate, on which thechip is assembled, having contacts for external connections; eachcontact including: a contact area with copper; an alloy layer coveringthe contact area, the alloy layer including copper/tin alloys andcopper/nickel/tin alloys, metallurgically attached to the copper areaand substantially free of regions of unalloyed nickel; thecopper/nickel/tin alloys including (Cu, Ni, Au)₆Sn₅ intermetalliccompound; a reflow element comprising tin metallurgically attached tothe alloy layer; and the substrate further having a second contact areawith copper and a region over the copper including nickel and gold; thesemiconductor chip mechanically assembled on the substrate.
 2. Thedevice according to claim 1 wherein the copper/tin alloys include Cu₆Sn₅intermetallic compound.
 3. The device according to claim 1 wherein thereflow element further comprises one or more metals selected from agroup consisting of lead, silver, bismuth, indium, zinc, copper, nickel,and antimony.
 4. The device according to claim 1 wherein the substratecontacts are defined by windows in a solder mask.
 5. The deviceaccording to claim 1 wherein the reflow elements are attached to thealloy layer area across the entire contact area.
 6. The device accordingto claim 1, wherein copper/nickel/tin alloys are adjacent the coppercontact area.
 7. The device according to claim 6, wherein the copper/tinalloys are adjacent the copper/nickel/tin alloys near the copper contactarea.
 8. The device of claim 1, in which the gold member is a section ofa gold wire.
 9. The device of claim 8, in which the gold wire forms astitch bond at the second contact area.
 10. The device of claim 1, inwhich the second contact area is free of solder material.
 11. A devicecomprising: a substrate having contacts on a first surface; each contacthaving a contact area with a copper surface, substantially free ofregions of unalloyed nickel, metallurgically attached to an alloy layerincluding copper/nickel/tin alloys and copper/tin alloys; the alloylayer further including a (Ni, Cu)₆Sn₅ intermetallic compound and aCu₆Sn₅ intermetallic compound; a solder element including tinmetallurgically attached to the alloy layer; and a semiconductor chipattached to the substrate on a second surface opposite the firstsurface.
 12. The device of claim 11, in which the alloy layer furtherincludes a (Ni, Cu, Au)₆Sn₅intermetallic compound.
 13. The device ofclaim 11, in which the contact areas are defined with a solder mask. 14.The device of claim 11, in which the second surface has bond pads. 15.The device of claim 14, in which a gold wire is stitched bonded to afirst bond pad.
 16. The device of claim 15, in which the first bond padhas a nickel layer and a gold layer over a copper layer.